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AP Chemistry (Period 1) Assignments

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Assignment

Attached below is a more detailed list and released AP FRQs of the topics we've covered for the final.  Of course review your notes as well.  Remember,to get to the released AP Chem questions you can follow this link (and scroll about half way down the page):
 

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Study your notes and homework on atomic structure and chemical bonding over the past week

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Complete the attached questions (Practice Atomic Structure) applying your understanding of Coulomb's Law as it relates to atomic structure.  Note that when we refer to ionization energy we are talking about the energy to remove the outermost electron (first ionization energy). When you see a reference to second ionization energy we mean the energy required to remove the next electron.  Third ionization energy would be the energy to remove the next one after that.  Keep in mind that each time you remove an electron, the positive charge of the nucleus can pull tighter on the remaining electrons (since there are less of them), and when removing an electron takes you down to the next lower energy level, the remaining electrons are now a closer distance to the nucleus.

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Complete the following two questions relating to energy levels of the Hydrogen atom.  See attached file

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For homework over the break, read and outline chapters 7,8, and 9 on atomic structure and chemical bonding.  We will look at these topics as we finish the fall semester.  If you don't have your book with you over the break, I will post an alternate assignment.  Keep checking

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Assessment Today - Gas Behavior (current topic) and Solution Stoichiometry (review topic). 
 
  • Study all your Gas Behavior FRQs (except 2012.2 and 2005B.2) and the enrichments.
  • Look over the strategies pages I prepared for you (the second one is attached here).
  • Study your last assessment (solution stoichiometry) writing balanced net ionic equations in solution and doing a stoichiometry problem.
Both enrichments and the second set of FRQs are due today.
For complete released answer keys google search this: "ap central released chemistry exams"
Remember, I am available for tutoring Thursday.

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Complete the AP Chem FRQ released questions handed out in class on Monday. I will write a "strategies" page like I did for the last one, but it will take me a day.  Look for the posting on Tuesday
 
Remember, we will have Enrichment on Wednesday morning and Assessment  on Gas Behavior (the new topic) and solution stoichiometry (review topic) on Friday.

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Complete the AP FRQ Gas Behavior questions (2 sheets) passed out in class.  The best approach is to
  1. try the problems yourself or with a partner
  2. Then look at the strategies page I have included as an attachment here.  It goes through each of the parts of each of the problems. 
  3. Then lastly, find the solution guides online.  All AP Chem released FRQs are out there.  They should not be hard to find.

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Expt #7 Molar mass by vapor density method today.  Early start (7:15 am).  ASA due and pre-lab ready.
 
Also, finish the remainder of the gas law/gas stoichiometry questions from the class worksheet (except the last two).

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I was not able to get a homework assignment up in a timely manner for tonight.  You should start reading Expt #7 to get an understanding of the lab technique and concepts.  Remember, we will have the early lab day this Thursday (ASA due and pre-lab ready on Thursday).

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Read sections 5.6 through 5.9 of your text.  Outline these sections and copy each of the formulas and sample exercises.
 
Bring your textbook today.  I will be out at a meeting.

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The attached file includes practice/review of first year gas law problems.  Review Chapter 5 exercises and gas law formulas.  For homework tonight, complete questions 1-8 of the attached file.

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Review Chapter 5 sections 5.1 through 5.3 and complete the attached worksheet on introductory gas law problems.  Answer key is included, but not the solutions to work them out.  That's your job.

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We are ready to begin a study of gas behavior.  This subject is heavily quantitative. For homework, read your textbook sections 5.3 through 5.5.  Copy the sample exercises in those sections (there are 13 of them), and then copy the calculations and solutions to those problems.  Look them over thoroughly and  make notes for yourself on any calculation/solution that you feel you need extra help with and we will go over them together in class.

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Assessment Today- Net Ionic Equations (including redox titration in acid solution) and stoichiometry of reactions (precipitation, redox titration, redox, acid-base neutralization)
 
Homework is to review your
  • net ionic equations (all types)
  • practice redox titration/stoichiometry worksheet
  • solution stoichiometry worksheet (answer key is attached below
  • and write net ionic equations for each of the chemical reactions from the solution stoichiometry worksheet (except #7)
A note about the answer key to the "solution stoichiometry worksheet":  questions #1,3, 8, and 9 are all theoretical yield of a product based on limiting reactants.  In first year chem, we learned a certain way to attack limiting reactant problems.  This answer key shows an alternative way.  For each of those questions, the smaller answer is the correct answer.

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7:05 am Extra Credit Enrichment today (even though it is an even day) 7:05 am start time.
Net Ionic Equations/Redox Titration.
 
If you cant make it to early enrichment, you should still stop by today to pick up the handout to study from.

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Attached is a copy of the enrichment from Wednesday. 
Answer Key attached as four separate pages
 
Note that question #4 and #6 are limiting reactant/theoretical yield problems that are solved using the same strategy as the solution stoichiometry worksheet; however, for this assessment if you are asked to do a theoretical yield of a product, you will be given the limiting reactant.
 

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Complete questions 1,2,4 from the attached Redox stoichiometry worksheet (include them with question #3 which you already did).  Also, write net ionic equations for the following: 
  • sodium phosphate solution reacts with calcium nitrate solution
  • aluminum metal reacts with nitric acid solution
  • aluminum metal reacts with copper (II) sulfate solution
  • potassium bromide solution reacts with fluorine gas
  • nitrous acid solution reacts with potassium hydroxide solution
AFTER SCHOOL TUTORING TODAY and every Tuesday & Thursday

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Early Lab Start 7:15 am.  Experiment #35 Determination of iron by reaction with permanganate - redox reaction
 
ASA is due today and complete question 3 from the redox stoichiometry/redox titration worksheet attached below.

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 Expt #35 is moved to Friday due to the PSAT, but pre-lab still due today.
 
Have pre-lab ready (intro, materials methods, results data tables), including the optional "standardization of KMnO4"  ASA is not due until Friday. We need more background first.
 
Also, complete balanced net ionic equations for the Redox reactions in solutions from the AP Chem Reactions page
 
 

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  • Complete the remainder of Thursday's enrichment (attached here)
  • Read and outline section 4.9 of your text (oxidation-reduction reactions) and 4.10 (balancing oxidation-reduction reactions), and show the steps for balancing the MnO4- + Fe+2 reaction (page163) and sample exercise 4.19 (page 165).

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The attached file includes neutralization reactions for you to write balanced net ionic equations.  Use your strong acid and strong base rules from class today, and remember we do not dissociate weak acids or bases. Also, note that most of the reactions on the worksheet contain at least one weak acid or one weak base.  You only need to complete four questions of your choosing from #1 of the worksheet and three questions from #2 of the worksheet.
 
Reminder that tomorrow is enrichment 7:05 am (1 extra credit point)

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As a review of solution preparation and dilutions, complete selected questions from the attached file which includes four worksheets:
  • Dilutions worksheet: 1,3,5
  • Molarity practice: 2,4
  • Concentration Worksheet: 4
  • Making Solutions Practice Worksheet: 2,3

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For homework, finish the Practice Gravimetric Analysis worksheet questions 1 and 3. Reminder, FRQ assessment today based on topics we have covered to date:
  • combustion analysis for empirical and molecular formulas and formula of a hydrate for empirical formula of a hydrated salt.  Study "Practice Problems Chemical Composition" worksheet and AP FRQ 2006 #3 and 2008 #2
  • gravimetric analysis to determine % mass of a substance in an impure mixture by precipitation.  Study "Practice Gravimetric Analysis"worksheet and AP FRQ 2014 #1 and 2011 #2
  • colorimetric analysis of transition metal ions in solution using Beer's Law.  Study expt #5 and AP FRQ 2003 #5 and 2006 (Form B) #5 a-b
The assessment will feature two of the above topics. 

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Just posted this at 1:30 pm on Tuesday. 
 
Write balanced net ionic equations for each of the following precipitation reactions.  A solubility table is attached below, but realize that you will need to become familiar with the rules as the AP exam gets closer.  No solubility table on the AP exam.
 
  1. silver nitrate solution + potassium chromate solution
  2. barium nitrate solution + aluminum sulfate solution
  3. sodium hydroxide solution + copper (II) sulfate solution
  4. silver nitrate solution + calcium bromide solution
  5. magnesium nitrate solution + potassium hydroxide solution
  6. potassium iodide solution + lead (II) nitrate solution

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Early lab start this morning (ready to go at 7:15 am)
 
Complete (as best you can) the ASA for today's experiment "Colorimetric Determination of Copper."  Questions #2 and 4 are like the practice we did in class on Thursday.  Attachment below
 
Complete your pre-lab for the experiment as well: Introduction, Materials and Methods, and Results data tables.  Read the beginning parts of the additional attachment here titled: "Theory and Practice of Spectrophotometry..." to help with your introduction.  Note that the lab handout does not have data tables written for you.  As you read through the procedure, design your own data tables that would be appropriate.
 
Also complete net ionic equations for the other 4 precipitation reactions from the class handout (also attached below). #3,6,10,and 14.  Refer to your notes as needed.  we did #2 and 5 in class.
 
 

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Read and outline sections 4.1-4.6 in your AP Chem text and complete the attached worksheets that review types of chemical reactions

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Attached here are sample analyses of uncontrolled errors as promised
 
Assessment Today - Chemical Composition (Empirical formula, molecular formula, percentage composition) using a variety of techniques and strategies including: combustion analysis, driving the water from a hydrate, and gravimetric analysis by precipitation. 
 
The assessment tests your understanding in three areas: conceptual understanding of empirical formulas and the lab techniques, calculations (empirical formula, molecular formula, % composition), and qualitative analysis of uncontrolled errors that would lead to your result being too large or too small (no quantitative error analysis this time).
 
Here are good resources to review:
  • Today's enrichment, both sides including the questions about uncontrolled errors
  • The FRQs 2006.3a-c and 2008.2a-e
  • practice gravimetric analysis worksheet questions 4 and 5
  • practice problems chemical composition worksheet questions 1-3
  • ASA experiment #13 formula for the hydrate
  • composition of matter worksheet questions 7-9
Over the weekend, I will post sample answers to the uncontrolled errors questions from the enrichment page.

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Attached here are sample qualitative analysis of uncontrolled experimental errors as promised.  Both of them come from Thursday's enrichment.

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Enrichment opportunity today (Gravimetric Analysis/Combustion Analysis).  7:05 am.  Be on time for extra credit
 
For homework:
  • Finish the data analysis of your hydrated salt from lab today determining the formula for the hydrate. Note that since your data is experimental, it may not be super accurate and your mole ratio of water to salt may not be so close to a whole number for rounding.  Consider this, the greatest uncontrolled error you might have experienced today is not driving off all the water.  Think about the implications of that and how it would affect your mass values (too low or too high?) when you consider rounding up or down.
  • Complete the data analysis for experiment #3 (go through the calculations to determine the empirical formula for the magnesium oxide product from lab last week). There was some confusion about this as homework the last time.
  • Complete the two FRQ from class today: Hydrate (2008 #2a-c) and combustion analysis (2005 #3ai-iv)
Assessment on Empirical formula/molecular formula determinations using all the various strategies we have learned is planned for next Monday.

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For homework:
  • finish the combustion analysis problems from class today
  • complete the data analysis for experiment #3 (determining the empirical formula for the magnesium oxide product from lab today)
  • complete the "empirical formula for a hydrated salt" questions from the attached file.  This is review of a topic we covered in first year chem.  Since it has been a while, the worksheet includes an example problem worked out.

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Early lab start today. 7:15 am.  Experiment #3 Determination of Empirical Formula. Have your pre-lab work ready (introduction, materials and methods, and results data tables).
 
Also complete two more combustion analysis problems from the "Composition of Matter" sheet: #7 (note SO2 gas is also released, and #8 (this one is tougher, but give it a try.  Get % compositions for each element before you get the amount of oxygen.  Then get oxygen by difference of the % compositions).

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Complete your Advanced Study Assignment for Experiment #3 - Determination of an Empirical Formula for a Compound in your lab notebook (leave one page empty from the previous lab).  Just a note: if you open the attached version of the Experiment #3 here, the title will say Experiment #2, but it is the same lab.
 
Also, as a follow-up to the problem we completed in class (Empirical and Molecular Formulas #7), complete #5,6,9,10 from the same problem set.
 
And, please bring your lab manual and lab notebook.  We still need to put closure on Experiment #1.

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Today we did a quick review of determining empirical formulas from percent composition data.  For homework, complete question 1 (we did this one in class), 2, 3, 4, 8 from the attached file "Empirical-Molecular Formulas," and question 4 from the attached file "Composition of Matter."
 
Also, please bring your lab manual and lab notebook.  We need to put closure on Experiment #1.

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Quiz Error Analysis of a set of data today
 
For homework, download and complete the attached file which is a practice error analysis of a set of data. 
 
Please bring the kinetics page of the summer assignment, your own answer page for the kinetics, and the answer key which is posted here under files. We may go over more today.
 
Also bring your lab manual and lab notebook as we plan to go over Experiment #1 today.

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Quiz Error Analysis of a set of data is postponed until next Monday.
 
Please print the kinetics page of the summer assignment, your own answer page for the kinetics, and the answer key which is posted here under files.
 
For homework, download and complete the attached worksheet which is a review of chemical formulas and names.  Search through chapter 2 for reference tables.
 
In class we will be going over Experiment #1 today, so please bring your lab manual and your lab notebook with the experiment.

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Complete your outline of chapter 2 of the text and turn in today.
 
Today we will carryout Experiment #1 which you prepared for last Friday.  Please make sure everything is complete and ready to go. The Experiment #1 advanced study assignment is due at the beginning of the period.
 
We will go over error analysis of the "Thickness of Foil" if time permits today.  If not, then Thursday's quiz will be postponed.

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Read Chapter 1 of Zumdahl (AP Chem text) and do challenge problems 85,88,90 page 35-36)
 
I will be out today.  Please bring your text book, lab manual and your college lab notebook to class today.  In class today we will:
  • Prepare the lab write-up for experiment #1: Densities of Liquids and Solids
    • Advanced Study Assignment
    • Introduction, materials and methods, and prepare results data tables
  • begin reading and outlining chapter 2 of your Zumdahl text.
 

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Please read the AP Chemistry course syllabus, safety instructions, and the Laboratory Report Format found on the right side of this page under "Files." Complete the section of the syllabus that asks for names and signatures (should be on the third page) and the signature page for safety instructions and return both today.
 
Read Chapter 1 of Zumdahl (AP Chem text) and do challenge problems 82,83,84 page 35-36)

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If you have not already submitted your final piece for the summer assignment (composition, reactions and stoichiometry), please email it to me today to avoid being late.